diff --git a/hemp-bioplastic/index.html b/hemp-bioplastic/index.html index 9562869..1492ab9 100644 --- a/hemp-bioplastic/index.html +++ b/hemp-bioplastic/index.html @@ -43,6 +43,29 @@ .honest-box b { color: #F44336; } + sup a { + text-decoration: none; + color: #CDDC39; + font-weight: bold; + } + sup a:hover { + text-decoration: underline; + } + .footnotes { + font-size: 0.85em; + line-height: 1.6; + } + .footnotes ol { + padding-left: 1.5em; + } + .footnotes li { + margin-bottom: 0.75em; + } + .footnotes li:target { + background: rgba(205, 220, 57, 0.1); + padding: 0.25em; + border-left: 3px solid #CDDC39; + }
@@ -70,7 +93,7 @@-Petroleum plastic breaks a cycle. Hemp bioplastic closes one. Sun grows hemp. Hemp yields cellulose. Cellulose gets pressed into bioplastic. Bioplastic serves its purpose. Discarded bioplastic composts in 3-6 months. Compost feeds soil. Soil grows hemp. Every output becomes an input. +Petroleum plastic breaks a cycle. Hemp bioplastic closes one. Sun grows hemp. Hemp yields cellulose. Cellulose gets pressed into bioplastic. Bioplastic serves its purpose. Discarded bioplastic composts in 3-6 months.[4] Compost feeds soil. Soil grows hemp. Every output becomes an input.
-Hemp grows in 120 days. One acre yields roughly 4 tons of dry stalk (conservative — research plots hit 8-12 tons, but plan for 4). That stalk contains two parts: bast fiber (outer bark, 30% of stalk, 77% cellulose) & hurd (inner woody core, 70% of stalk, 44% cellulose). Both contain cellulose. Getting it out requires chemistry. +Hemp grows in 120 days. One acre yields roughly 4 tons of dry stalk[1] (conservative — research plots hit 8-12 tons, but plan for 4). That stalk contains two parts: bast fiber (outer bark, 30% of stalk, 77% cellulose) & hurd (inner woody core, 70% of stalk, 44% cellulose).[2] Both contain cellulose. Getting it out requires chemistry.
-Stalks get decorticated (separated into bast & hurd). Fiber soaks in sodium hydroxide (NaOH / lye) at 80-90°C for 2-5 hours to dissolve lignin. Acid wash removes hemicellulose. Bleach & filtration leave clean cellulose. Mix with glycerol as plasticizer (15% by weight). Hot press at 150-240°C into molds. +Stalks get decorticated (separated into bast & hurd). Fiber soaks in sodium hydroxide (NaOH / lye) at 80-90°C for 2-5 hours to dissolve lignin.[12] Acid wash removes hemicellulose. Bleach & filtration leave clean cellulose. Mix with glycerol as plasticizer (15% by weight). Hot press at 150-240°C into molds.
-From 4,000 kg of dry stalk, expect roughly 1,680 kg of extractable cellulose, yielding approximately 1,200 kg of finished bioplastic. Roughly 30% conversion efficiency from stalk to product. Rest goes to waste liquor, lignin (compostable), & hurd byproducts (animal bedding, hempcrete, garden mulch). +From 4,000 kg of dry stalk, expect roughly 1,680 kg of extractable cellulose,[3] yielding approximately 1,200 kg of finished bioplastic. Roughly 30% conversion efficiency from stalk to product. Rest goes to waste liquor, lignin (compostable), & hurd byproducts (animal bedding, hempcrete, garden mulch).
-Pure cellulose bioplastic stays brittle & water-sensitive. It biodegrades in 3-6 months — a feature for disposables, a fatal flaw for anything meant to last. Most commercial "hemp plastic" products actually blend hemp fiber (30-50%) with corn-based PLA or even petroleum polypropylene. A 100% hemp-derived polymer exists at laboratory scale but has not reached commercial viability. +Pure cellulose bioplastic stays brittle & water-sensitive. It biodegrades in 3-6 months[4] — a feature for disposables, a fatal flaw for anything meant to last. Most commercial "hemp plastic" products actually blend hemp fiber (30-50%) with corn-based PLA or even petroleum polypropylene. A 100% hemp-derived polymer exists at laboratory scale but has not reached commercial viability.[5]
@@ -138,11 +161,11 @@ Pure cellulose bioplastic stays brittle & water-sensitive. It biodegrades in 3-6-An average American household consumes roughly 200 kg of plastic per year. That number includes everything — durable goods, synthetic textiles, electronics, plumbing, & packaging. Hemp bioplastic cannot replace most of that. So how much can it actually replace? +An average American household consumes roughly 200 kg of plastic per year.[6] That number includes everything — durable goods, synthetic textiles, electronics, plumbing, & packaging. Hemp bioplastic cannot replace most of that. So how much can it actually replace?
-Packaging & disposable containers account for roughly 100-115 kg per household per year. Of that, hemp bioplastic could realistically substitute for items where brittleness & moisture sensitivity stay acceptable — food trays, plant pots, dry-goods containers, bags, disposable cutlery. That narrows to roughly 30-50 kg per household per year. +Packaging & disposable containers account for roughly 100-115 kg per household per year.[7] Of that, hemp bioplastic could realistically substitute for items where brittleness & moisture sensitivity stay acceptable — food trays, plant pots, dry-goods containers, bags, disposable cutlery. That narrows to roughly 30-50 kg per household per year.
@@ -251,15 +274,15 @@ No single household can justify a $5,000 decorticator or a chemical extraction s
-Heartland Hemp Cooperative (Indiana/Ohio/Kentucky) — farmer-owned co-op, $500/share, pooling resources to purchase a shared decorticator. 20-40 member-farmers within 150-mile radius. +Heartland Hemp Cooperative (Indiana/Ohio/Kentucky) — farmer-owned co-op, $500/share, pooling resources to purchase a shared decorticator. 20-40 member-farmers within 150-mile radius.[9]
-Western Fiber (California) — converted a cooperative cotton gin to process hemp in off-season. Existing infrastructure, shared costs. Achieved ~8 tons/acre from irrigated fields. +Western Fiber (California) — converted a cooperative cotton gin to process hemp in off-season. Existing infrastructure, shared costs. Achieved ~8 tons/acre from irrigated fields.[10]
-Winona's Hemp (White Earth, Minnesota) — Indigenous-led initiative building decortication on tribal land across northern plains. Partners with tribes across multiple reservations. +Winona's Hemp (White Earth, Minnesota) — Indigenous-led initiative building decortication on tribal land across northern plains. Partners with tribes across multiple reservations.[11]
-Hemp bioplastic costs 2-3x more than petroleum plastic today. No subsidies, no infrastructure, no scale. +Hemp bioplastic costs 2-3x more than petroleum plastic today.[8] No subsidies, no infrastructure, no scale.
-Corn-based PLA (another bioplastic) costs $2-3/kg & fell 50% in price since 2007 as infrastructure scaled. Hemp bioplastic could follow that trajectory. But today it sits at $5/kg — roughly double PLA & triple petroleum plastic. At community cooperative scale, labor costs drop. At household scale, labor costs dominate & make each kg more expensive in time than in dollars. +Corn-based PLA (another bioplastic) costs $2-3/kg & fell 50% in price since 2007 as infrastructure scaled.[13] Hemp bioplastic could follow that trajectory. But today it sits at $5/kg — roughly double PLA & triple petroleum plastic. At community cooperative scale, labor costs drop. At household scale, labor costs dominate & make each kg more expensive in time than in dollars.
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